Responses inline
A gluster volume cannot span multiple clusters. If you want to create a separate cluster with the Broadwell nodes, then create a new gluster volume using the disks from these nodes - i.e do not expand the existing volume by adding bricks from the new servers.
2) I'm using a separate VLAN+domain name for gluster, and oVirt is proposing me to use the gluster (storage) domain names as the new hosts identifier.You can add hosts using the Add new host flow - and provide the FQDN that you want as management interface, and later associate the gluster VLAN with a network that has "gluster" role.Please keep in mind that you cannot add this to a new cluster in oVirt if you have already used bricks from these servers on existing volume in another cluster