Hi Sahina and Yedidyah,
Thanks for the information and offers of help. I am pleased to report that I've resolved the issue I had, thanks to the prompting your requests gave me, and everything is functional. I shall attempt to explain what happened and how I fixed it.
This then gave me a different error message when trying to add Host02 or Host03, "no available server in the cluster to probe the new server", which only further confirmed that it was a Gluster issue, as was suggested.
After some hair-pulling and wondering, I finally discovered that, in Compute > Hosts > Host01 under the General tab, it was complaining that Gluster was not active (even though it was running). I clicked the action item link to resolve that, and oVirt appeared to start actually managing the Gluster service. I could then add my other hosts, import the existing storage domains, and everything appears good now.
Thanks again for the assistance and prompting me towards the right places to help me resolve it.
Regards,
Adam