If you're signing into Keycloak at "https://<your
engine/ovirt-engine-auth/", e.g. to set up additional users who will manage oVirt,
you sign in as just 'admin', not 'admin@ovirt'.
If you're signing in to oVirt at "https://<your engine>/ovirt-engine/"
and clicking "Administration Portal", then the user is indeed admin@ovirt.