Hello,
I'm installing a new test oVirt environment and I'm going to use CentOS 6.5
for the engine.
I just verified that the instructions at
http://www.ovirt.org/Quick_Start_Guide
work correctly and exactly the same for CentOS too.
Previously only Fedora was referred and the first-time coming users could
feel confused...
so I took the time to add Red Hat Enterprise Linux and CentOS.
Feel free to revise and correct the page
Gianluca